Wednesday 23 August 2017

The Physics of Polishing -



Physics (from Ancient Greek: φυσική (ἐπιστήμη) phusikḗ (epistḗmē) "knowledge of nature", from φύσις phúsis"nature"

 [: a natural science that involves the study of matter and its motion through space and time, along with related concepts such as energy and force.]

The clear coat will generally measure between 1.5 - 2.5 mils. The clear coat provides gloss plus physical protection from the elements, including ultraviolet (UV) radiation, which is in the upper level of a cured clear coat. 

Most car manufacturers will only allow ~ 25% of the clear-coat thickness to be removed without voiding the paint warranty and long-term durability problems becoming an issue. That means that if you started off with 50µ of clear coat (this will vary by vehicle manufacturer) you would only be able to remove <12µ without voiding the paint warranty and possibly having a re-paint.

New or Aged Paint
 Be cognizant there are major differences between the way a freshly painted and an aged surface will react to abrasives, which are usually aluminium oxide or silicon carbide Abrasive products are designed for newly painted surfaces and for use by body shops not  paint correction/renovation.  Both types of paint require a different approach and perhaps even a different abrasive product. 

It is all too easy to remove too much paint once it is ‘aged’ with the inherent danger of removing it’s ultra violet protection. Paint surface polishing limits - 6.26 mµ (0.25 Mil) < clear coat removal. Any more then this will result in paint failure and a re-paint. Most compound type abrasives are formulated to remove sanding marks from fresh paint not paint renovation

Pad Brasivness

Pads have a grit number, which is in effect how abrasive it is (this grit number is based upon how much grit is contained in a sqare ince of finishing (sandpaper) paper. So an abrasivene can be affected by the grit number of the pad.The grit size of sandpaper is usually stated as a number that is inversely related to the particle size. A small number such as 20 or 40 indicates a coarse grit, while a large number such as 1500 indicates a fine grit.

Polishing Abrasives

I’ve spent many hours meeting and speaking with Engineers, paint chemists, product formulators, and abrasive manufacturers and polishing pad manufacturers and have gained insights into paint surface polishing that has afforded me an understanding of how all these things interact to form a process, on a scientific level paint polishing is the sum of all these parts.
Polish a paint surface correctly (regardless of the machine we are using) the goal is leave a series of scratching that is so fine that it becomes imperceptible to the naked eye.

Backing Plate / Pad Motion

Inertial mass [: is mainly defined by Newton's law, the all-too-famous F = ma, which states that when a force F is applied to an object, it will accelerate proportionally, and that constant of proportion is the mass of that object]

To determine the inertial mass, you apply a force of F Newton’s to an object, measure the acceleration in m/s2, and F/a will give you the inertial mass m in kilograms.
Centripetal and Centrifugal force should not be confused with each other, they are opposites

Centripetal [: is a force which acts on a body moving in a circular path and is directed towards the centre around which the body is moving]

Centrifugal [: a force, equal and opposite to the centripetal force, drawing a rotating body away from the center of rotation, caused by the inertia of the body]

A vibration free tool will fatigue the user less and can reduce the risk of long-term health problems such as carpel tunnel syndrome (see article “Health Hazards of Detailing”) and it also reduces most of the factors that cause wear to the motor.

Random orbital polishers, by design, are unbalanced. You have a large mass (backing plate/pad/spindle) that is orbiting around a central axis point. The further the mass is away from the axis, the greater the unbalance, the more intense the vibration becomes (see diagram Centripetal Force)
Dynamic balance [: occurs when the force on all sizes of the axis are equal and then the tool operates with very little ‘out of balance’ vibration] the uneven distribution of mass in a rotating body contributes to the unbalance.

Centre of gravity [: a point from which the weight of a body or system may be considered to act. In uniform gravity it is the same as the centre of mass.

Excessive vibration in rotating machinery can cause unacceptable levels of noise and substantially reduce the life of shaft bearings. Hence, the ideal would be to remove all causes of vibration and run the unit totally smooth. Unfortunately, in actual practice, this ideal cannot be achieved and some inherent cause of vibration, or unbalance, will remain.

The best you can do is to reduce this unbalance to a level that will not adversely affect the bearing life and will reduce noise levels to an acceptable level. The unbalance is caused by an effective displacement of the mass centre line from the true axis caused by some mass eccentricity in the unit.

The benefits of a large orbit or elliptical offset (15-21 mm) is that more centripetal force is created as the backing plate orbits, so the backing plate will rotate more than a similar machine featuring a smaller elliptical offset. A machine featuring a large stroke delivers increased speed of backing plate motion using the same orbits per minute.

A large stroke elliptical offset increases movement of the baking plate / pad, which increases the speed of the backing because they are travelling a greater distance in the same amount of time. The resultant speed also increases the development of kinetic energy, therefore levelling is more consistent.

This type of movement helps to remove residue (oxidized paint, spent abrasives, etc.) more readily than a small elliptical offset and extends the workable life of the pad. This culminates in a very smooth polishing action; making it extremely comfortable to use even when working for prolonged periods.

A majority of random orbital machines use an elliptical offset between 3.0-8.0 mm. It is generally accepted that a smaller stroke leaves a more refined finish, but experience shows that this type of movement doesn’t readily clear (oxidized paint, spent abrasives, etc. ) polishing debris, thereby blocking the pores of the pad and placing debris between the pad and the paints surface negatively impacting the abrasive backing plate / pad motion

Why Low Vibration is Important
Vibration can cause a range of conditions called hand-arm vibration syndrome (HAVS). The best known is vibration white finger (VWF), but vibration also links to specific diseases such as carpal tunnel syndrome.

HAVS and VWF usually result from damage to the fine capillaries in the end of your fingers which reduces blood flow to the extremities of fingers and hands which take on a 'blanched' effect appearing white.

It has been proven that operators face significant risk of muscle, joint and nerve damage caused by the inherent vibration of power tools. By reducing the amount of vibration you can reduce muscle and joint fatigue as well as the potential risk for permanent damage, as described in ISO 5349-1:2001- Mechanical vibration -Measurement and evaluation of human exposure to hand-transmitted vibration.

Declaration of Vibration Emission
The Supply of Machinery (Safety) Regulations require that, among other information, suppliers of machinery must declare the vibration emission of their tools and machines. The purpose of declaring such information is to allow purchasers and users of tools and machinery to make informed choices regarding the vibration emission of a potential purchase

The method of declaring vibration emission is to apply a standard test to a machine or tool. The purpose of the standard test is to provide a repeatable and reproducible method of estimating vibration emission. This will bring the process of emission declaration in line with the techniques for assessment of human exposure to hand transmitted vibration as defined in EN ISO 5349:2001 and as called for in the requirements for quantification of exposure in the Control of Vibration at Work Regulations (2005).

Surface Lubrication

Glycerin (C3H8O3) [: is a simple polyol compound. It is a colorless, odorless, viscous liquid that is sweet-tasting and non-toxic. The glycerol backbone is found in all lipids known as triglycerides.It’s trihydric sugar, being the alcoholic component of fats ]

Surface (Contact) Area
The distance around the circle is a circumference (c) The distance across the circle is the diameter (d). The radius (r) is the distance from the centre to a point on the circle. (π= 3.14), d = 2(r), c = d = 2 (p) r, A = π (r) 2 Even a minor change in pad diameter makes a big difference in surface area.

A pad should be designed to efficiently use its surface area. Foam pads that have lines, squares, circles, or dimples cut out of the pad face, means there is less actual surface area in contact with the paint surface. Area = π (r2) 6-inch pad area = 18.842 sq.ins, a 4-inch pad 12.46 sq.ins.

Kinetic (Heat) and machine energy (Speed) and surface pressure applied over a smaller area, which results in faster correction. A further consideration of pad diameter has to do with distribution of the machine weight and applied pressure.

Another design parameter that determines how much surface area actually contacts the paint when using foam pads is the amount of pores per inch it features (commonly referred to as PPI). More pores, larger pores, thinner walls between the pores, or how stiff the walls are all affect how much foam contacts the paint during the buffing process

Block wet sanding (finishing paper and a sanding block) which ensures a consistent pressure over the surface contact area, this is the most effective tool for paint defect removal because of its linear process you abrade the paint surface flat until the defects are removed.

Pad Velocity (Speed)
The larger the pad, the greater the pad velocity at an identical RPM; V = RPM (Area) A - 6.5-inch = 20.423 sq.ins V= 24,507 inches per minute (IPM) Pad velocity is also substantially increased with a larger diameter pad, which increase its abrasive ability at the outer edge; 8-inch =25.136 sq.ins. V= 30,163 RPM

Pressure / Pad Compression
Depending on the types of surface abrasions you're dealing with, increase pressure is necessary; otherwise most of the kinetic energy of the machine will be absorbed by the pad (especially foam) and not transferred to the paint surface.

Just remember that more pressure equals more aggressive, so be careful around ridges and raised surfaces Maintain the same pressure and work the product in, it may take three or four passes to complete before the residue can be removed. Once you see the desired results move on to the next area, or repeat the process as necessary.

The required pressure applied to obtain optimum results to adequately compress the pad (50%) and obtain uniform abrasion is usually in the range of 10 to 15 lbs. (a random orbital buffer will stall at approximately 20 pounds of applied force) use just enough pressure to keep the pad rotating at 1-2 rotations per second.

To compress a 6-inch pad 50% requires you increase the total force by the ratio of its surface areas; Ratio = [Ï€ (radius2)] / [Ï€ (radius2)] = 2.25 as much force, almost 34 pounds).

With the smaller pad you're applying the same force, at a constant speed but over a smaller, more concentrated area, which will induce friction and greater abrasion abilities to the polish, both these abilities require a certain amount of caution as it’s possible to abrasion burn the paint.

Constant Pressure -  Foam Pads have a layer of engineered, instant rebound foam between the pad and the backing plate. This layer acts as a cushion or shock absorber between the machine, the operator and the surface being worked on. It absorbs off-axis motion while maintaining a constant and uniform pressure on the surface; Lake Country Mfg. Constant Pressure technology allows even a neophyte detailer to achieve professional-like results.

Foam Pad Size (Area and Applied Pressure)
Different pad sizes can have an impact on how the buffer breaks down a polish, as it applies its dynamic friction over less area, control, better manoeuvrability, and how fast you can cover an area.
Smaller pads in general will offer you more control with any machine polisher, as it can reduce the tendency for the buffer to hop or skip on the paint. Smaller pads also make it easier to manoeuvre buffers in tighter areas and closer to trim pieces.

The low profile 5.5-inch buffing pads pack the same CCS technology and performance into a compact, highly effective size that works best with dual action polishers and air sanders. Use with a 5 - inch moulded urethane backing plate for excellent flexibility and balance by Lake Country (LC) manufacturing

Assuming equal speed, radius and foam compression (50% - 15 pounds of force applied) the difference between 4- inch and 6 - inch pads is their different surface area = π (r2) (4-inch = 12.46 sq.ins / 6-inch = 28.26 sq.ins) and therefore surface kinetic (or dynamic) friction applied and surface pressure applied 4-inch = 3.75 lbs per sq.ins. - 6-inch = 2.5 lbs per sq.ins. Even a minor change in pad diameter makes a big difference in surface area.

Actual Speed (RPM)

Formula - RPM (C) = V
Speed = Revolutions per minute, C = circumference (2(π) (r)), V = velocity
Area 7.5 -inch at 1,800 rpm (usable area 6- inches)
Speed - 1,800 (rpm) (6" diameter times pi = 6 -inch x 3.14) x 18.84 = 33,912.
So, using the same formula, and a problem of: X (unknown rpm) x 25.12 (8" diameter times pi = 8 x 3.14) = 33,912) then; 33,912 / 25.12 = 1,350 actual speed rpm

Heat from Kinetic (or dynamic) Friction

[Energy in a system may take on various forms (e.g. kinetic, potential, heat, light). Kinetic friction, or surface resistance induced heat; an often misunderstood concept of polishing / compounding; abrasives require friction to breakdown, not heat; heat is just a resultant of friction between two surfaces. Kinetic friction is required to ‘level’ paint, which is simply the removal of paint to the lowest point of the paint defect] 

Polishing a paint surfaces transfer’s kinetic friction induced heat to the paint surface, thermoplastic polymers have both tensile strength (a linear stress-strain relationship) and elongation (elasticity) which allow the surface to flex, expand and contract in accordance to surrounding temperatures, solvents, resins and other ingredients in polishes will expand causing the paint film surface to expand

As the metal substrate expands the paint moves with it, due to its elasticity, thereby becoming elongated (thinner) this is part of the cause of friction induced ‘burn’, you’re applying pressure and an abrasive to a less dense (‘thinner’) paint surface, excess friction induced heat can cause the paint surface to burn, blister, haze, and cause excessive swirls.

Plastic has a much lower rate of thermal conductivity than metal, so it absorbs heats at a far greater rate and therefore is subject to localized ‘spot’ heating.

Polishes and compounds do not need heat per se for the abrasives to polish a surface, whether they be diminishing or non-diminishing abrasive, they require both pressure and friction Kinetic friction induced heat can cause a rapid temperature rise; (i.e. initial surface temp 80.F, friction heat attained with the polisher stationary and a cutting foam pad at 1,100 RPM for approx. ten seconds the friction induced heat attained would be around ~104.F)

When a localized spot is significantly hotter that the surrounding area you have a potential problem, the paint temperature can be checked by utilizing an instant read-out infrared ‘gun type’ digital thermometer

A finishing pad will not provide as much friction as a cutting foam pad (less surface resistance) although they will both produce friction induced heat, whereas a wool pad, due to their composition, creates less friction induced heat but more kinetic friction (due to its fibrous structure) than most foam pads. Be cognizant that with high ‘spot’ temperatures the pad structure will cause scratching that is forced deep into the clear coat.

You should try to maintain as cool a surface temperature as possible when polishing, use your hand to provide a general idea of how much heat is being transferred by kinetic (friction) energy; it will of course be at a higher temperature than ambient. An orbital polisher tends to concentrate higher temperatures at the centre of the pad, whereas a rotary the heat builds up more toward the outer edge of the pad.

Kinetic Friction induced heat can cause a rapid temperature rise; (i.e. initial surface temp 80.oF, friction heat attained with the polisher stationary and a cutting foam pad at 1,100 RPM for approx. ten seconds the friction induced heat attained would be around 104.oF) the paint temperature can be checked by utilizing an instant read-out infra-red ‘gun type’ digital thermometer, paint surface ‘spot’ temperature should be limited to 110.oF <

In accordance with the Society of Automotive Engineers (SAE) a localized (spot) temperature of > 115.oF will cause the urethane clear coat to soften and the foam pad will cause scratching that is forced deep into the clear coat. (See also the first law of thermodynamics et al)

The result of creating heat in an OEM clear in excess of 145 F, creates thermo-stressing of the resin system and as a result the clear coat would suffer premature failure in a short amount of it's life.

Polishing Freshly Applied Paint
When a urethane clear coat is sprayed its outermost surface, measuring a few nanometres in thickness, sustains microscopic fractures when it comes into contact with air. These fractures are microns or nanometres in width and thus too small to be seen with the unaided eye. 

Freshly applied paint that in the outgas stage, is still full of evaporating solvents, and is usually less dense (soft) despite the additives used (hardener) once a catalyst, kinetic energy (friction heat) is added, it causes the paint film to expand, temporarily hiding scratches, this is often the reason for a body-shops bad reputation of returning vehicles that have sanding scratches in newly applied paint that should have been removed.

Be cognizant when polishing newly applied paint the kinetic energy (heat) from a foam pad can also cause solvent engorgement, which causes the paint film to thin due to the expansion of the evaporating gases, applied rotational force may also cause the paint to tear Kinetic friction (heat) is transferred to a solvent (IPA or fresh paint solvents) causing it to both expand (Charles' law; also known as the law of volumes) the paint film and soften it.

Automotive paint is classified as a semi-permeable membrane; it has both tensile strength and elongation (elasticity) newly painted surfaces are soft and full of out gassing solvents, resin binders and additives, as well as and water.

Polish contains solvents, which soften the paint film, kinetic surface friction and applied downward pressure transfers its energy into heat / torque (force to rotate an object about an axis), which could result in the alteration of the paint films bond between its substrate, causing it to delaminate or tear?



The heat makes the gasses expand (pV = nRT) the expanding gases go through a phase transition (change in density) and to relive this increased pressure they (a) rupture the paint film surface, causing small fissures (similar to solvent pop) The heat may cause the gaseous vapours to expand, but not enough to break through the hardening clear coat. Once the vapour has evaporated, it may leave a void between the basecoat and the clear. Therefore, you have a cloudy spot where the clear and base is no longer adhered together. If this is the case, the clear coat will delaminate in the future.

Once the outgas process is complete automotive coatings (paint) becomes a semi-solid permeable membrane, being a polymer (elastomers) it remains flexible while retaining its tensile strength, to enable it to expand and contract to follow temperature fluctuations of the substrate (elongation). 

Kinetic friction and its associated heat can cause a rapid temperature rise (i.e. initial surface temp 80.oF, heat attained with a cutting foam pad at 1,100 RPM for approx. ten seconds is approx. 104.oF) the paint temperature can be checked by utilizing an instant read-out infrared  thermometer, paint surface spot’ temperature should be limited to 110.oF <



Force diagram
Arrows are vectors indicating directions and magnitudes of forces. W is the force of weight, N is the normal force, F is an applied force of unidentified type, and Ff is the force of kinetic friction which is equal to the coefficient of kinetic friction times the normal force. Since the magnitude of the applied force is greater than the magnitude of the force of kinetic friction opposing it, the block is moving to the left.

Applied Pressure
The pad needs to have an even distribution of pressure applied to it; depending on the types of surface abrasions you're dealing with, increase pressure as necessary. Just remember that more pressure equals more aggressive, so be careful around ridges and raised surfaces
Maintain the same pressure and work the product in, it may take three or four passes to complete before the residue can be removed. Once you see the desired results move on to the next area, or repeat the process as necessary.
The required pressure applied to obtain optimum results to adequately compress the pad (50%) and obtain uniform abrasion is usually in the range of 10 - 15 lbs. (a random orbital buffer will stall at approximately 20 pounds of applied force) To compress a 6-inch pad 50% requires you increase the total force by the ratio of its surface areas

Ratio = [Ï (radius2)] / [Ï (radius2)] = 2.25 as much force, almost 34 psi). With the smaller pad you're applying the same force, at a constant speed but over a smaller, more concentrated area, which will induce an increase in friction and greater abrasion abilities to the polish / pad combination, both these abilities require a certain amount of caution as it’s possible to ‘strike through’ (friction burn) the paint.

With the smaller pad you're applying the same force, at a constant speed but over a smaller, more concentrated area, which will induce an increase in friction and greater abrasion abilities to the polish / pad combination, both these abilities require a certain amount of caution as it’s possible to ‘strike through’ (friction burn) the paint.

Hardness
So how can a dense (hard) clear coat be so easily scratched?
It’s a matter of physics, not material density (material hardness). Force acts through a body that has a surface area; if the surface area is really small while maintaining an equal force, the pressure becomes astronomical and the object under pressure capable of penetrating the surface of an otherwise tough material.

Newton's third law of motion [: when a first body exerts a force F1 on a second body, the second body simultaneously exerts a force F2 = −F1 on the first body. This means that F1 and F2 are equal in magnitude and opposite in direction]

That’s why a micro fine thread that is twice as fine as silk and a 100 times finer than a human hair, in an otherwise soft towel will scratch your paint. And the same reason a mosquito can penetrate a rhino hide with its proboscis (stinger).

If you press down on your paint finish with your palm it feels really hard and tough, but that’s because the surface area of your palm is relatively large and what you’re actually feeling is the resistance of the steel underneath the paint. Try pressing your thumb nail into the paint with the same amount of force you used with your palm, if you dare.

Personal Protection Equipment (PPE)

1. Eye Protection: I would strongly advise the wearing of safety glasses or visor (prescription eyeglasses are not a substitute) when operating any machine polisher. OSHA requires employers to ensure the safety of all employees in the work environment. Eye and face protection must be provided whenever necessary to protect against chemical, environmental, radiological or mechanical irritants and hazards.
 2. Hearing Protection; the constant pitch of a polishing machine could affect your hearing so wearing ear plugs would be wise to protect you from hearing loss.
 3. Hand Protection; Gloves- with the verity of chemicals a detailer uses on a daily basis wearing chemical-resistant gloves resist penetration and permeation, and will provide protection against dermatitis and chemical burns. Gloves can provide protection, but they must be chosen with care, the proper selection matched to the hazard is critical as they offer a much needed protective barrier when handling cleaning chemicals such as wheel cleaners and multipurpose cleaners.
Nitrile gloves are made of synthetic latex. They contain no latex proteins and offer excellent resistance to punctures and tears. Nitrile gloves are three times more puncture resistant than rubber and can be used to offer superior resistance to many types of chemicals.
Chemical-resistant gloves resist penetration and permeation, and cam protect against dermatitis, chemical burns and corrosion. Nitrile gloves are three times more puncture resistant than latex rubber and can be used to offer superior resistance to many types of chemicals. Unlike other latex gloves, Nitrile gloves have low resistance to friction and are very easy to slide on –
Clove Chemical Resistance Chart - http://www.adenna.com/pdf/ChemicalsResistance.pdf
 4. Respiratory Protection (N95): Materials such as aluminium oxide (Aluminium oxide is on EPA's TRI list if it is a fibrous form) or silicon carbide (Nuisance particulate-Accumulation in lungs) used in polishes and compounds, and powdered fillers
Crystalline silica (polishes and compounds) poses a serious inhalation hazard because it can cause silicosis and Isocyanate clear coat residue represent a hazard to your lungs and may cause respiratory distress. Use a NIOSH-approved half face respirator equipped with a combination filter cartridge should be worn while using them

Consult the current 3M Respiratory Selection Guide for additional information or call 1-800-243-4630 for 3M technical assistance.

References
1. Correlation between vibration emission and vibration during real use - Polishers and sanders. Prepared by the Health and Safety Laboratory Health and Safety Executive 2007
Related Articles

Other Authors
1. Kevin Brown - http://www.buffdaddy.com/buffingpads

 I would like to think that these articles become an asset to anyone who is new to detailing and to professionals alike, as well as industry experts who seek to advance their knowledge.
I hope the above article was informative. By having some understanding of the ‘What’ and ‘Why’ as well as the ‘How’ along with a little science to help you understand how the chemicals we use react, you can achieve the results you desire.
I would appreciate it if you would share this article as it helps other detailers further their knowledge. Questions and/ or constructive comments are always appreciated.

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